{"id":12222,"date":"2021-02-11T14:25:21","date_gmt":"2021-02-11T17:25:21","guid":{"rendered":"https:\/\/publicaciones.udt.cl\/?post_type=pub&#038;p=12222"},"modified":"2021-02-11T14:25:21","modified_gmt":"2021-02-11T17:25:21","slug":"synergy-between-ni-and-co-nanoparticles-supported-on-carbon-in-guaiacol-conversion","status":"publish","type":"pub","link":"https:\/\/publicaciones.udt.cl\/pub\/synergy-between-ni-and-co-nanoparticles-supported-on-carbon-in-guaiacol-conversion\/","title":{"rendered":"Synergy between Ni and Co Nanoparticles Supported on Carbon in Guaiacol Conversion"},"content":{"rendered":"<p>BLANCO, E., DONGIL, A.B., ESCALONA, N.:<br \/>\n<a href=\"https:\/\/www.mdpi.com\/2079-4991\/10\/11\/2199\" target=\"_blank\" rel=\"noopener\"><strong>Nanomaterials 2020, 10(11), 2199.<\/strong><\/a><\/p>\n<p><strong>DOI:\u00a0<\/strong>10.3390\/nano10112199<\/p>\n<h3>Abstract<\/h3>\n<p style=\"text-align: justify;\">Nickel-cobalt bimetallic catalysts supported on high surface area graphite with different Ni:Co ratios (3:1, 2:1 and 1:1) and the monometallic Ni and Co were prepared by wetness impregnation method. The catalysts were tested in hydrodeoxygenation (HDO) of guaiacol in the liquid phase at 50 bar of H<sub>2<\/sub> and 300 \u00b0C. The materials were characterized by N<sub>2<\/sub> adsorption\u2013desorption, XRD, TEM\/STEM, H<sub>2<\/sub>-TPR, and CO-chemisorption to assess their properties and correlate them with the catalytic results. The activity was higher on the bimetallic catalysts and followed the trend NiCo<sub>2:1<\/sub>\/G \u223c NiCo<sub>3:1<\/sub>\/G &gt; NiCo<sub>1:1<\/sub>\/G &gt; Co\/G &gt; Ni\/G. Also, selectivity results showed that Ni was more active in the hydrogenation favoring cyclohexanol production from phenol, while this was inhibited on the Co-containing catalysts. Hence, the results showed that synergy was created between Ni and Co and that their interaction, properties, and catalytic performance depend on the metals\u2019 ratio.<\/p>\n<div class=\"fusion-button-wrapper\"><a class=\"fusion-button button-flat fusion-button-default-size button-default fusion-button-default button-1 fusion-button-default-span fusion-button-default-type fusion-animated\" data-animationType=\"slideInLeft\" data-animationDuration=\"0.3\" data-animationOffset=\"top-into-view\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"https:\/\/doi.org\/10.3390\/nano10112199\"><span class=\"fusion-button-icon-divider button-icon-divider-left\"><i class=\" fa fa-external-link\" aria-hidden=\"true\"><\/i><\/span><span class=\"fusion-button-text fusion-button-text-left\">see more<\/span><\/a><\/div>\n","protected":false},"excerpt":{"rendered":"<p>BLANCO, E., DONGIL, A.B., ESCALONA, N.: Nanomaterials 2020, 10(11), 2199. DOI:\u00a010.3390\/nano10112199 Abstract Nickel-cobalt bimetallic catalysts supported on high surface area graphite with different Ni:Co ratios (3:1, 2:1 and 1:1) and the monometallic Ni and Co were prepared by wetness impregnation method. The catalysts were tested in hydrodeoxygenation (HDO) of guaiacol in the liquid phase at [&hellip;]<\/p>\n","protected":false},"featured_media":10051,"parent":0,"menu_order":0,"comment_status":"open","ping_status":"closed","template":"","kw":[2294,2139,1026,1040],"yr":[2157],"dp":[973],"au":[1023],"ty":[959],"class_list":["post-12222","pub","type-pub","status-publish","has-post-thumbnail","hentry","kw-bimetallic-","kw-cobalt-","kw-hydrodeoxygenation","kw-nickel","yr-2157","dp-bioenergy","au-escalona-n","ty-isi"],"metadata":{"_last_editor_used_jetpack":"classic-editor","_edit_lock":"1613066650:2","_edit_last":"2","_thumbnail_id":"10051","onesignal_meta_box_present":"1","onesignal_send_notification":"","onesignal_modify_title_and_content":"","onesignal_notification_custom_heading":null,"onesignal_notification_custom_content":null,"_fusion":{"show_first_featured_image":"yes","fimg":{"width":"","height":""},"post_links_target":"no","bg_full":"no","display_header":"yes","header_bg_full":"no","blog_width_100":"no","main_padding":{"top":"","bottom":""},"content_bg_full":"no","image_rollover_icons":"default","bg_repeat":"default","header_bg_repeat":"repeat","displayed_menu":"default","slider_type":"no","wooslider":"0","elasticslider":"0","page_title_bar":"default","content_bg_repeat":"default"},"_yoast_wpseo_content_score":"30","_yoast_wpseo_estimated-reading-time-minutes":"1","_yoast_wpseo_primary_kw":"2294","_yoast_wpseo_primary_yr":"2157","_yoast_wpseo_primary_dp":"973","_yoast_wpseo_primary_au":"1023","_yoast_wpseo_primary_ty":"959","avada_post_views_count":"53","avada_today_post_views_count":"1","avada_post_views_count_today_date":"17-11-2024"},"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v23.6 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Synergy between Ni and Co Nanoparticles Supported on Carbon in Guaiacol Conversion &#8226; Publicaciones UDT<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/publicaciones.udt.cl\/pub\/synergy-between-ni-and-co-nanoparticles-supported-on-carbon-in-guaiacol-conversion\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Synergy between Ni and Co Nanoparticles Supported on Carbon in Guaiacol Conversion &#8226; Publicaciones UDT\" \/>\n<meta property=\"og:description\" content=\"BLANCO, E., DONGIL, A.B., ESCALONA, N.: Nanomaterials 2020, 10(11), 2199. 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