{"id":10552,"date":"2018-09-03T12:21:03","date_gmt":"2018-09-03T15:21:03","guid":{"rendered":"https:\/\/publicaciones.udt.cl\/?post_type=pub&#038;p=10552"},"modified":"2018-09-03T12:23:16","modified_gmt":"2018-09-03T15:23:16","slug":"treatment-of-a-mixture-of-chloromethoxyphenols-in-hypochlorite-medium-by-electrochemical-aops-as-an-alternative-for-the-remediation-of-pulp-and-paper-mill-process-waters","status":"publish","type":"pub","link":"https:\/\/publicaciones.udt.cl\/pub\/treatment-of-a-mixture-of-chloromethoxyphenols-in-hypochlorite-medium-by-electrochemical-aops-as-an-alternative-for-the-remediation-of-pulp-and-paper-mill-process-waters\/","title":{"rendered":"Treatment of a mixture of chloromethoxyphenols in hypochlorite medium by electrochemical AOPs as an alternative for the remediation of pulp and paper mill process waters"},"content":{"rendered":"<p>SALAZAR, C.; SIRES, I.; ZAROR, C.:<br \/>\n<strong><a href=\"https:\/\/link.springer.com\/journal\/12678\/4\/4\/page\/1\" target=\"_blank\" rel=\"noopener\">Electrocatalysis 4:4 (2013) 212-223.<\/a><\/strong><\/p>\n<p><strong>DOI:\u00a0<\/strong>10.1007\/s12678-013-0130-9<\/p>\n<h3>Abstract<\/h3>\n<p style=\"text-align: justify;\">Here, 100\u00a0mg\u00a0L<sup>\u22121<\/sup> of dissolved organic carbon of aromatics including chloromethoxyphenols were prepared by exposition of a mixture of guaiacol, syringol, and vanillin in 200\u00a0mM NaClO at pH\u00a03.0 and 25\u00a0\u00b0C for 14\u00a0h and further degraded by electrochemical advanced oxidation processes (EAOPs) like anodic oxidation with electrogenerated H<sub>2<\/sub>O<sub>2<\/sub> (AO-H<sub>2<\/sub>O<sub>2<\/sub>), electro-Fenton (EF), and photoelectro-Fenton (PEF). Electrolyses were performed with a cell containing either a Pt or boron-doped diamond (BDD) anode and an air-diffusion cathode at constant current density. Oxidants were hydroxyl radicals (<sup>\u2022<\/sup>OH) formed at the anode surface from water oxidation and in the bulk from Fenton\u2019s reaction between added Fe<sup>2+<\/sup> and H<sub>2<\/sub>O<sub>2<\/sub> generated at the cathode, as well as active chlorine species produced from the anodic oxidation of HClO. Oxychlorine ions like ClO<sub>3<\/sub> <sup>\u2212<\/sup> using Pt and ClO<sub>3<\/sub> <sup>\u2212<\/sup>\u2009+\u2009ClO<sub>4<\/sub> <sup>\u2212<\/sup> using BDD were detected in the electrolyzed solutions. A poor mineralization was found using the Pt\/air-diffusion cell, with increasing relative oxidation ability in the sequence AO-H<sub>2<\/sub>O<sub>2<\/sub>\u2009&lt;\u2009EF\u2009&lt;\u2009PEF. In contrast, overall mineralization was achieved in all EAOPs using the BDD\/air-diffusion cell due to the larger amounts of highly oxidizing <sup>\u2022<\/sup>OH generated at BDD. For this latter system, the effect of UVA light, current density, and NaClO and\/or Fe<sup>2+<\/sup> concentration on the mineralization rate was examined. Up to 11 chloroderivatives of the parent molecules including four chlorophenols, six chloromethoxyphenols, and one chloromethoxynaphthalene were identified by GC\u2013MS. The removal of these aromatics in AO-H<sub>2<\/sub>O<sub>2<\/sub> with Pt or BDD was monitored by UV\u2013vis spectrophotometry, HPLC, and GC\u2013MS.<\/p>\n<div class=\"fusion-button-wrapper\"><a class=\"fusion-button button-flat fusion-button-default-size button-default fusion-button-default button-1 fusion-button-default-span fusion-button-default-type fusion-animated\" data-animationType=\"slideInLeft\" data-animationDuration=\"0.3\" data-animationOffset=\"top-into-view\" target=\"_blank\" rel=\"noopener noreferrer\" href=\"http:\/\/dx.doi.org\/10.1007\/s12678-013-0130-9\"><span class=\"fusion-button-icon-divider button-icon-divider-left\"><i class=\" fa fa-external-link\" aria-hidden=\"true\"><\/i><\/span><span class=\"fusion-button-text fusion-button-text-left\">see more<\/span><\/a><\/div>\n","protected":false},"excerpt":{"rendered":"<p>SALAZAR, C.; SIRES, I.; ZAROR, C.: Electrocatalysis 4:4 (2013) 212-223. DOI:\u00a010.1007\/s12678-013-0130-9 Abstract Here, 100\u00a0mg\u00a0L\u22121 of dissolved organic carbon of aromatics including chloromethoxyphenols were prepared by exposition of a mixture of guaiacol, syringol, and vanillin in 200\u00a0mM NaClO at pH\u00a03.0 and 25\u00a0\u00b0C for 14\u00a0h and further degraded by electrochemical advanced oxidation processes (EAOPs) like anodic oxidation [&hellip;]<\/p>\n","protected":false},"featured_media":10051,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","kw":[1484,1485,1486,1487,1488,1489],"yr":[1202],"dp":[1007],"au":[1009],"ty":[959],"class_list":["post-10552","pub","type-pub","status-publish","has-post-thumbnail","hentry","kw-anodic-oxidation","kw-bdd-anode","kw-chloromethoxyphenols","kw-electro-fenton","kw-hypochlorite-medium","kw-photoelectro-fenton","yr-1202","dp-environment-and-services","au-zaror-c","ty-isi"],"metadata":{"_edit_lock":"1535988071:2","_edit_last":"2","_thumbnail_id":"10051","pyre_show_first_featured_image":"no","pyre_fimg_width":"","pyre_fimg_height":"","pyre_portfolio_width_100":"default","pyre_video":"","pyre_image_rollover_icons":"default","pyre_link_icon_url":"","pyre_post_links_target":"no","pyre_related_posts":"default","pyre_share_box":"default","pyre_post_pagination":"default","pyre_author_info":"default","pyre_post_meta":"default","pyre_post_comments":"default","pyre_slider_type":"no","pyre_slider":"0","pyre_wooslider":"","pyre_revslider":"0","pyre_elasticslider":"0","pyre_slider_position":"default","pyre_avada_rev_styles":"default","pyre_fallback":"","pyre_demo_slider":"","pyre_main_top_padding":"","pyre_main_bottom_padding":"","pyre_hundredp_padding":"","pyre_display_header":"yes","pyre_header_100_width":"default","pyre_header_bg_color":"","pyre_header_bg_opacity":"","pyre_header_bg":"","pyre_header_bg_full":"no","pyre_header_bg_repeat":"repeat","pyre_displayed_menu":"default","pyre_display_footer":"default","pyre_display_copyright":"default","pyre_footer_100_width":"default","pyre_sidebar_position":"default","pyre_sidebar_sticky":"default","pyre_sidebar_bg_color":"","pyre_page_bg_layout":"default","pyre_page_bg_color":"","pyre_page_bg":"","pyre_page_bg_full":"default","pyre_page_bg_repeat":"default","pyre_wide_page_bg_color":"","pyre_wide_page_bg":"","pyre_wide_page_bg_full":"default","pyre_wide_page_bg_repeat":"default","pyre_page_title":"default","pyre_page_title_breadcrumbs_search_bar":"default","pyre_page_title_text":"default","pyre_page_title_text_alignment":"default","pyre_page_title_custom_text":"","pyre_page_title_text_size":"","pyre_page_title_line_height":"","pyre_page_title_custom_subheader":"","pyre_page_title_custom_subheader_text_size":"","pyre_page_title_font_color":"","pyre_page_title_100_width":"default","pyre_page_title_height":"","pyre_page_title_mobile_height":"","pyre_page_title_bar_bg_color":"","pyre_page_title_bar_borders_color":"","pyre_page_title_bar_bg":"","pyre_page_title_bar_bg_retina":"","pyre_page_title_bar_bg_full":"default","pyre_page_title_bg_parallax":"default","_yoast_wpseo_content_score":"90","_yoast_wpseo_primary_kw":"1484","_yoast_wpseo_primary_yr":"1202","_yoast_wpseo_primary_dp":"1007","_yoast_wpseo_primary_au":"1009","_yoast_wpseo_primary_ty":"959","sbg_selected_sidebar":["0"],"sbg_selected_sidebar_replacement":[""],"sbg_selected_sidebar_2":["0"],"sbg_selected_sidebar_2_replacement":[""],"_fusion":{"show_first_featured_image":"yes","post_links_target":"no","slider_type":"no","slider":"0","revslider":"0","elasticslider":"0","display_header":"yes","header_bg_full":"no","header_bg_repeat":"repeat","sbg_selected_sidebar":["0"],"0":"","sbg_selected_sidebar_2":["0"]},"avada_post_views_count":"39","avada_today_post_views_count":"1","avada_post_views_count_today_date":"27-10-2024"},"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v23.6 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Treatment of a mixture of chloromethoxyphenols in hypochlorite medium by electrochemical AOPs as an alternative for the remediation of pulp and paper mill process waters &#8226; Publicaciones UDT<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/publicaciones.udt.cl\/pub\/treatment-of-a-mixture-of-chloromethoxyphenols-in-hypochlorite-medium-by-electrochemical-aops-as-an-alternative-for-the-remediation-of-pulp-and-paper-mill-process-waters\/\" \/>\n<meta property=\"og:locale\" content=\"en_US\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Treatment of a mixture of chloromethoxyphenols in hypochlorite medium by electrochemical AOPs as an alternative for the remediation of pulp and paper mill process waters &#8226; Publicaciones UDT\" \/>\n<meta property=\"og:description\" content=\"SALAZAR, C.; SIRES, I.; ZAROR, C.: Electrocatalysis 4:4 (2013) 212-223. 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